Product Name: Bismuth Citrate
Chemical Formula: C6H5BiO7
Synonyms: Bismuth(3+) citrate
CAS Number: 813-93-4
Recommended Use: Laboratory chemicals, pharmaceutical preparations, industrial applications
Manufacturer Details: Provided on supply documentation
Emergency Contact: Refer to local poison control or emergency medical services
UN Number: Not regulated
Email Contact: Manufacturer customer service address
GHS Classification: Not classified as hazardous under GHS
Health Hazards: May cause mild irritation to eyes and skin, ingestion may cause stomach upset including nausea and vomiting; inhalation of dust could irritate airways
Environmental Hazards: Toxic to aquatic environments in high concentrations
Physical Hazards: Stable under normal conditions; dust can cause annoyance
Pictograms: None required under current guidelines
Signal Word: None required
Hazard Statements: May cause skin and eye irritation; avoid breathing dust
Precautionary Statements: Do not eat, drink or smoke when handling; work in a ventilated area; wash thoroughly after handling
Chemical Identity: Bismuth Citrate
Component: Bismuth citrate, 100%
Impurities: Trace amounts of other bismuth salts are possible; refer to batch-specific analysis
Molecular Weight: 398.09 g/mol
Inhalation: Remove to fresh air; provide oxygen if breathing is difficult; seek medical help if symptoms persist
Skin Contact: Wash skin thoroughly with water and mild soap; seek medical attention if irritation develops
Eye Contact: Rinse cautiously with water for at least 15 minutes, lifting eyelids; get medical attention if irritation remains
Ingestion: Rinse mouth, do not induce vomiting unless directed by medical personnel; seek medical advice especially for children or those with health conditions
Most Important Symptoms: Irritation, upset stomach, minor respiratory effects
Notes to Physician: Provide symptomatic and supportive care; no specific antidote known
Suitable Extinguishing Media: Carbon dioxide, dry chemical, foam, water spray
Unsuitable Extinguishing Media: None known relating to Bismuth Citrate
Specific Hazards: Material is not combustible; decomposition can release carbon oxides, bismuth oxides
Protective Equipment for Firefighters: Wear self-contained breathing apparatus, full protective gear
Advice for Firefighters: Move containers from area if possible; cool unopened containers with water spray to prevent build-up of pressure
Personal Precautions: Avoid breathing dust, wear protective gloves and masks; evacuate unprotected people from the area
Environmental Precautions: Prevent further leakage or spillage if safe; avoid discharge into drains, water sources
Spill Cleanup Methods: Sweep up and place in suitable, labelled containers for disposal; clean surface thoroughly to remove residual material
Additional Advice: Use non-sparking tools and ventilate the area; dispose of waste as per regulatory requirements
Safe Handling: Use in well-ventilated spaces; avoid contact with eyes, skin and clothing; avoid inhalation of dust; wash hands before eating or drinking
Safe Storage: Keep container tightly sealed in a cool, dry, well-ventilated area away from incompatible substances like oxidizing agents
Storage Temperature: Store at ambient temperature, away from direct sunlight
Incompatibilities: Strong oxidizers, acids
Container Requirements: Use corrosion-resistant, airtight containers; label appropriately
Exposure Limits: No occupational exposure limit values specifically for Bismuth Citrate; use lowest practical exposure
Engineering Controls: Use local exhaust ventilation or process enclosures to minimize airborne dust
Personal Protective Equipment: Safety glasses with side shields, chemical-resistant gloves, lab coat
Respiratory Protection: Dust mask or NIOSH-approved particulate respirator if dust is generated
Environmental Exposure Controls: Avoid release to landscaping, soil, or external drains; contain spills and collect for disposal
Appearance: White to off-white powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Slightly acidic to neutral (variable in solution)
Melting Point: Not well defined, decomposes
Boiling Point: Decomposes before boiling
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Not flammable
Vapor Pressure: Negligible at room temperature
Relative Density: ~2.3 g/cm³
Solubility: Slightly soluble in water
Partition Coefficient (n-octanol/water): No data
Auto-ignition Temperature: Not applicable
Decomposition Temperature: >250°C
Viscosity: Not applicable to solid powders
Chemical Stability: Stable under recommended storage conditions
Possibility of Hazardous Reactions: No hazardous reactions expected during normal use
Conditions to Avoid: Excessive heat, exposure to strong acids or bases
Incompatible Materials: Strong oxidizers, reducing agents, acids
Hazardous Decomposition Products: Thermal decomposition may produce bismuth oxides, carbon oxides, and potentially irritating fumes
Likely Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Toxicity: Low oral and dermal toxicity; LD50 (Oral, Rat): > 5,000 mg/kg
Chronic Toxicity: Repeated exposure can affect kidney and liver function
Skin Corrosion/Irritation: May cause slight irritation
Serious Eye Damage/Irritation: May cause mild eye irritation
Respiratory Sensitization: Not classified
Germ Cell Mutagenicity: No data
Carcinogenicity: Not listed by IARC, NTP, OSHA
Reproductive Toxicity: No significant evidence of teratogenicity or mutagenicity in animal studies
Target Organs: Liver, kidney (at high chronic doses)
Ecotoxicity: Bismuth Citrate is harmful to aquatic life if released in large quantities
Persistence and Degradability: Poorly biodegradable; persists in sediment
Bioaccumulation: Bismuth metal has a low potential for bioaccumulation; citrate breakdown products are biodegradable
Mobility in Soil: Moderate, may leach through soil depending on local environmental conditions
Other Adverse Effects: Heavy metal concerns for long-term build-up in aquatic environments
Waste Disposal Methods: Collect and place in clearly labeled, sealed containers; transfer to licensed chemical waste disposal facility
Disposal of Packaging: Decontaminate containers if possible; dispose of in accordance with local and national regulations
Other Disposal Considerations: Do not dispose into water sources or household garbage; use hazardous waste contractors where required
UN Number: Not applicable; not regulated as a hazardous material under ICAO, IATA, IMDG, or DOT
Proper Shipping Name: Bismuth Citrate
Transport Hazard Class: Not classified
Packing Group: Not assigned
Marine Pollutant: Not listed
Special Transport Precautions: Prevent container damage; avoid spillage during transport
Substances of Very High Concern: Not listed under REACH
OSHA Status: Substance not specifically regulated
TSCA Inventory: Present
EU EINECS / ELINCS: Listed
SARA Title III: Not subject to SARA Title III reporting
California Prop 65: Not listed as a substance known to cause cancer or reproductive toxicity
Other Regulations: Observe all national and local environmental protection regulations
