Product Name: Calcium Citrate Malate
Chemical Formula: Ca6C6H5O72·xH2O
Common Uses: Dietary calcium supplement, food additive, fortification agent in beverages
Manufacturer: Listed on packaging or shipping papers
Emergency Contacts: Refer to regional poison control center, manufacturer emergency number
Recommended Use: Addition to food products, supplements, pharmaceutical grade calcium source
Synonyms: CCM, Tricalcium Citrate Malate
CAS Number: 142606-53-9
Supplier Company Details: Detailed on label and shipping documents
Restrictions on Use: Not suitable for individuals with hypercalcemia, severe kidney disease
GHS Classification: Not classified as a hazardous substance under GHS
Signal Word: None required
Hazard Statements: Non-toxic, considered safe for intended use
Precautionary Statements: Avoid excessive inhalation or ingestion
Physical Hazards: Mild dust can cause mechanical irritation
Health Hazards: May cause mild eye and respiratory irritation if dust levels are high
Environmental Hazards: Not known to pose significant aquatic or terrestrial hazard
Main Symptoms: Temporary discomfort from dust exposure (itchy eyes, mild coughing)
Chemical Identity: Calcium Citrate Malate
Purity: >97%
Key Components: Calcium (Ca), Citric Acid, Malic Acid
Formula by Weight: Approximate molar ratio of 6 parts calcium, 2 parts citrate, 1 part malate
Impurities: Trace moisture, small quantities of sodium or potassium (from processing)
Additives: None in pure forms; blended products may contain stabilizers such as anti-caking agents
Inhalation: Move to fresh air, rinse mouth, seek medical attention if symptoms persist
Ingestion: Rinse mouth with water, drink water to dilute, medical attention unnecessary unless large amounts consumed
Skin Contact: Wash with water and mild soap, remove contaminated clothing if irritation occurs
Eye Contact: Rinse thoroughly with water for several minutes, medical attention if irritation continues
Most Important Symptoms: Mild irritation, sneezing, coughing or watery eyes
Special Notes to Physician: Treat symptoms, product lacks significant systemic toxicity
Suitable Extinguishing Media: Water, dry chemical, foam, or carbon dioxide
Unsuitable Extinguishing Media: None known for this substance
Specific Hazards in Fire: Product itself will not burn; in a fire, may release minor fumes from packaging
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus if dust becomes airborne
Firefighting Instructions: Evacuate area, prevent dust dispersion, stay upwind of fire
Combustion Products: Carbon oxides, calcium oxides under extreme conditions
Personal Precautions: Wear dust mask, safety glasses, gloves to minimize exposure
Environmental Precautions: Prevent bulk amounts from entering waterways
Containment & Cleanup: Sweep up material, avoid creating dust, transfer to labeled waste container
Methods for Cleaning Up: Small spills—mop or damp wipe; large spills—use HEPA vacuum or wet sweep
Disposal of Collected Material: Dispose in accordance with local, state, federal regulations
Preventative Measures: Minimize dust to reduce inhalation risk and housekeeping concerns
Handling Precautions: Use only in well-ventilated area or under dust extraction
Minimize Dust Generation: Pour gently or use closed transfer systems
Recommended Storage Conditions: Tightly closed container, dry, cool, and well-ventilated location
Incompatible Materials: Strong acids and oxidizers
Safe Transfer Procedures: Use scoop or dispenser designed to limit powder escape
Storage Temperatures: Between 15°C and 30°C for optimum shelf life
Other Recommendations: Keep away from moisture sources to prevent clumping or degradation
Exposure Limits: No OSHA PEL or ACGIH TLV set for this compound
Engineering Controls: Local exhaust ventilation, HEPA filtration if airborne dusts present
Personal Protective Equipment (PPE): Dust mask or N95 respirator for heavy exposure, safety goggles to prevent eye contact, disposable gloves
Housekeeping: Regular cleaning of surfaces and equipment to control dust
Workplace Hygiene: Do not eat, drink, or smoke in areas of use; wash hands thoroughly after handling
Clothing Recommendations: Protective overgarments where dust exposure risk is high
Appearance: White to off-white fine powder or crystalline granules
Odor: Odorless
Odor Threshold: Not applicable
pH (5% solution): 6.0 to 8.0
Melting Point: Decomposes before melting
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Non-flammable
Vapor Pressure: Not applicable
Solubility in Water: Slightly soluble
Specific Gravity/Density: 1.5–2.0 g/cm3
Partition Coefficient (n-octanol/water): Not determined
Autoignition Temperature: Not self-igniting
Decomposition Temperature: Above 200°C (with emission of CO2)
Chemical Stability: Stable under recommended storage conditions
Reactivity: Low chemical reactivity
Possible Hazardous Reactions: None under usual handling
Conditions to Avoid: Exposure to strong acids, strong oxidizers, high humidity
Incompatible Materials: Strong acids can liberate carbon dioxide, strong oxidizers may affect product properties
Hazardous Decomposition Products: Carbon oxides and calcium oxide if overheated
Polymerization: Does not occur
Routes of Exposure: Inhalation, ocular contact, dermal contact, ingestion
Acute Toxicity: Low toxicity; large amounts can cause gastrointestinal upset
Skin Corrosion/Irritation: Possible mild irritation from direct contact
Serious Eye Damage/Irritation: Temporary physical irritation, not chemically caustic
Inhalation Effects: Dust may lead to coughing or throat irritation
Ingestion Effects: Well-tolerated in normal doses; excessive intake could create symptoms of hypercalcemia
Chronic Effects: Prolonged high intake could impact kidney function; consult medical advice for long-term supplementation
Carcinogenicity: Not listed by IARC, NTP, OSHA
Other Data: Allergenicity rare, but those sensitive to citrates should monitor intake
Ecotoxicity: Not considered toxic to aquatic life under normal environmental concentrations
Persistence and Degradability: Biodegradable, organic acids degrade naturally
Bioaccumulation Potential: Low; substance does not concentrate in organisms
Mobility in Soil: Dissolves slowly, unlikely to migrate through soil rapidly
Other Adverse Effects: Large spills may alter soil or water pH slightly if not diluted
Aquatic Data: Safe for use in foods, extremely low risk to aquatic environments at typical concentrations
Waste Handling: Dispose of in accordance with all applicable local, national regulations
Incineration: Unnecessary—standard landfill disposal is suitable for non-contaminated product
Small Quantity Disposal: Flush to drain with generous amounts of water if permitted
Bulk Disposal: Landfill if not recoverable; avoid uncontrolled release to environment
Container Disposal: Triple rinse and recycle or dispose of containers according to legal requirements
Special Precautions: Avoid dust release during handling of waste substances
UN Number: Not regulated as a hazardous material
UN Shipping Name: Not classified as dangerous goods
Transport Hazard Class: Not classified
Packing Group: Not assigned
Labeling Requirements: Standard product name and weight identification
Transport Precautions: Avoid moisture, prevent tearing of sacks or drums
Regulatory Information: Not subject to ADR, IMDG, IATA dangerous goods rules
EU Regulations: Listed under food additives (E333), not a hazardous substance by REACH
US Federal Regulations: FDA GRAS status, not subject to reporting under SARA Title III
Canada Regulations: Not a controlled product under WHMIS
International Inventories: Listed in major chemical inventories (TSCA, EINECS/ELINCS)
Restrictions: Intended solely for food, pharmaceutical, or industrial non-hazardous uses
Labeling for Use: Full product name, grade, batch number, and manufacturer details
Worker Communication: SDS must be accessible to all users and handlers at worksite
Other Relevant Standards: Compliance with ISO 22000 for food safety may apply in processing facilities
