Material Safety Data Sheet (MSDS) for CITROCOAT EP

1. Identification

Product Name: CITROCOAT EP
Recommended Use: Anti-corrosive epoxy coating for industrial and commercial applications
Manufacturer: CitroCoat Technologies, 459 Industrial Drive, Greenford, USA
Contact Information: Emergency Phone - 1-888-555-6372 (24/7 Hotline), Technical Questions - info@citrocoat.com
Product Code: EP211
Date MSDS Prepared: April 12, 2024

2. Hazard Identification

Hazard Class: Flammable Liquid, Category 3; Skin corrosion/irritation, Category 2; Eye damage/irritation, Category 2
Signal Word: Warning
Hazard Statements: Causes skin and eye irritation. May cause allergic skin reaction. Flammable. Vapors may cause drowsiness and dizziness.
Precautionary Statements: Wear protective gloves and eye protection. Avoid breathing vapors. Keep container tightly closed. Store away from ignition sources.
Pictograms: Flame, Exclamation Mark, Health Hazard
Potential Health Effects: Repeated exposure may lead to dermatitis. Eyes can experience redness or pain. Vapors can induce headaches if ventilation remains poor.

3. Composition / Information on Ingredients

Bisphenol A Epoxy Resin: 35–45%
Xylene: 8–15%, CAS #1330-20-7
Polyamide Hardener: 15–25%
Titanium Dioxide: 2–8%, CAS #13463-67-7
Ethylbenzene: 1–4%, CAS #100-41-4
Other Ingredients: Proprietary additives and solvents up to 100%

4. First Aid Measures

Inhalation: Move affected person to fresh air. If symptoms like nausea or drowsiness persist, consult a doctor.
Skin Contact: Remove contaminated clothing and wash skin with soap and water. Seek medical advice for lasting irritation or allergic response.
Eye Contact: Rinse eyes carefully with water for at least 15 minutes. Lift eyelids to ensure thorough cleansing. Get medical attention for persistent redness or discomfort.
Ingestion: Rinse mouth. Do not induce vomiting. Seek immediate medical attention, especially if large quantities are swallowed.

5. Fire-Fighting Measures

Suitable Extinguishing Media: CO2, dry chemical, foam
Unsuitable Extinguishing Media: Strong water jets
Hazards from Combustion: Burning may release formaldehyde, carbon monoxide, carbon dioxide, and phenolic compounds.
Protective Equipment for Firefighters: Use self-contained breathing apparatus and protective clothing. Cool sealed drums near fire with spray water.
Fire and Explosion Hazards: Vapors can ignite at room temperature, creating risk near open flames and hot surfaces. Flash point about 25°C.

6. Accidental Release Measures

Personal Precautions: Evacuate spill area. Ventilate if indoors. Use antistatic clothing and shoes
Environmental Precautions: Keep away from drains and surface waters.
Methods for Containment: Contain the spill with sand or earth. Prevent product from spreading.
Cleanup Procedures: Collect spilled material with non-sparking tools. Place in labeled containers for disposal. Wash contaminated surfaces with water and detergent. Dispose in accordance with regulations.

7. Handling and Storage

Handling: Use only with adequate ventilation. Avoid inhaling vapors and contact with skin or eyes. Ground containers to prevent static during transfer. Do not eat or drink while handling product.
Storage: Store in tightly closed containers. Keep cool, dry, and away from sources of ignition. Separate from oxidizers and food. Temperature between 5°C and 30°C.
Special Requirements: Keep out of reach of children. Store away from direct sunlight. Use spark-proof tools and explosion-proof equipment.

8. Exposure Controls and Personal Protection

Exposure Limits: Xylene ACGIH TLV 100 ppm TWA, Ethylbenzene ACGIH TLV 20 ppm TWA
Engineering Controls: Use local exhaust ventilation or fume hoods.
Respiratory Protection: Use NIOSH-approved respirators if ventilation remains insufficient.
Skin Protection: Wear nitrile gloves, long sleeves, and chemical-resistant apron.
Eye Protection: Use safety goggles and face shields.
General Hygiene: Wash hands before breaks and after handling. Remove contaminated clothing promptly.

9. Physical and Chemical Properties

Appearance: Viscous liquid, usually light gray or white
Odor: Mild aromatic
Odor Threshold: Detectable at 1–5 ppm (for xylene)
pH: Not applicable
Melting Point/Freezing Point: Not determined
Boiling Point: 135–145°C
Flash Point: 25°C (Closed cup)
Evaporation Rate: Moderate
Flammability: Flammable liquid
Vapor Pressure: 6–8 mm Hg at 25°C
Vapor Density: Heavier than air
Solubility: Insoluble in water; soluble in organic solvents
Partition Coefficient (n-octanol/water): Not available
Auto-ignition Temperature: About 470°C
Decomposition Temperature: Above 200°C
Viscosity: High, 800–1200 cps at 25°C

10. Stability and Reactivity

Chemical Stability: Remains stable under recommended handling and storage conditions
Possibility of Hazardous Reactions: May react exothermically with strong acids, bases, and oxidizers
Conditions to Avoid: Elevated temperatures, sparks, open flames, direct sunlight
Incompatible Materials: Mineral acids, peroxides, nitrates, strong alkalis
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, formaldehyde, toxic phenolics

11. Toxicological Information

Likely Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Acute Effects: Skin and eye irritation, headache, dizziness, possible nausea
Chronic Effects: Prolonged contact may cause dermatitis or respiratory sensitivity
Sensitization: Can cause allergic skin reaction in sensitive individuals
Carcinogenicity: Ethylbenzene classified as possible human carcinogen (IARC Group 2B)
Reproductive Toxicity: No data available
Information on Individual Components: Xylene can affect central nervous system. Bisphenol-A epoxy resins can trigger sensitization.

12. Ecological Information

Ecotoxicity: Xylene toxic to aquatic life with long-lasting effects. Epoxy components harmful to fish and invertebrates.
Persistence and Degradability: Main ingredients resist rapid breakdown. Some components may bioaccumulate.
Mobility in Soil: Low mobility due to viscosity and tendency to absorb to organic matter.
Other Adverse Effects: Spilled coatings can create surface films that reduce oxygen exchange in water bodies.

13. Disposal Considerations

Waste Handling: Follow federal, state, and local regulations for hazardous waste disposal. Collect residues and spent containers separately.
Recommended Methods: Incinerate in approved facility. Do not release into sewers or watercourses.
Empty Container Precautions: Do not reuse unless professionally cleaned. Puncture and dispose in permitted site.
Disposal of Cleanup Materials: Treat absorbent materials as hazardous waste. Label and store for pickup.

14. Transport Information

UN Number: 1263
UN Proper Shipping Name: Paint Related Material
Transport Hazard Class: 3 (Flammable Liquids)
Packing Group: III
Environmental Hazards: Regulated as marine pollutant under IMDG
Special Precautions for User: Keep upright. Seal tightly. Do not transport with foodstuffs.
Emergency Response Guide: Refer to ERG 128 for spill, fire, or exposure management during transit.

15. Regulatory Information

OSHA: Hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
TSCA: All ingredients listed or exempt
SARA Title III: Section 313: Xylene, Ethylbenzene listed
California Prop 65: Contains chemicals known to the State of California to cause cancer or reproductive toxicity
WHMIS (Canada): Class B2 (Flammable), Class D2B (Toxic material causing other toxic effects)
EPA: RCRA waste code D001 (Ignitable); D018 for xylene
International Regulations: Complies with EU REACH, classified as hazardous per Regulation (EC) No. 1272/2008