Product Name: CITROFOL AII
Chemical Name: Triisobutyl citrate
Synonyms: TIBC, Acetyl tributyl citrate, Acetic acid, 2-(acetyloxy)-1,2,3-propanetricarboxylic acid, triisobutyl ester
CAS Number: 77-90-7
EC Number: 201-067-0
Recommended Use: Plasticizer for polymers, coatings, adhesives,
Supplier: (Contact details, address, emergency telephone number)
Classification: Not classified as hazardous under Regulation (EC) No 1272/2008 (CLP/GHS)
Hazard Statements: Not considered hazardous to health or environment
Labelling Elements: No pictogram, signal word, or hazard statements required
Potential Health Effects: Inhalation, ingestion, eye, and skin contact could cause mild irritation in sensitive individuals
Environmental Effects: Product shows low environmental hazard risk in standard use
Chemical Name: Triisobutyl citrate
Concentration: >99%
Impurities: Trace substances below threshold reporting limits
Additive Components: None declared
Inhalation: Move to fresh air. If symptoms develop, consult a physician
Skin Contact: Wash skin thoroughly with water and soap
Eye Contact: Rinse cautiously under running water for several minutes. Remove contact lenses if present and easy to do so. Seek medical advice if symptoms persist
Ingestion: Rinse mouth. Do not induce vomiting. Drink water in small sips. Seek medical attention if feeling unwell
Important Symptoms: Mild irritation possible. No significant acute or delayed effects reported
Suitable Extinguishing Media: Foam, carbon dioxide, dry chemical, water spray
Unsuitable Extinguishing Media: Water jet
Special Hazards: Combustion can release carbon monoxide, carbon dioxide, possible organic vapors
Protective Equipment: Firefighters use self-contained breathing apparatus and protective suit
Advice: Cool containers with water spray to prevent damage from heat exposure
Personal Precautions: Avoid contact with skin, eyes. Ensure adequate ventilation
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Avoid contaminating soil and waterways
Containment: Contain spillage. Absorb with inert material such as sand or universal binder
Cleaning Up: Collect and place in suitable, labeled containers for waste disposal. Clean contaminated area with plenty of water
Handling Conditions: Handle with care, minimize exposure. Use local exhaust or general room ventilation to reduce exposure
Storage Requirements: Store in tightly closed, original container in a dry, cool, well-ventilated area
Incompatibilities: Keep away from strong oxidizers, acids
Hygiene Measures: Wash hands thoroughly after handling
Storage Temperature: Recommended storage between 15°C and 30°C
Exposure Limits: No established occupational exposure limits
Engineering Controls: Use local exhaust ventilation as needed
Personal Protective Equipment: Safety glasses with side shields, chemical-resistant gloves, appropriate protective clothing
Respiratory Protection: Not typically required with adequate ventilation. In poorly ventilated areas, use approved respirators
Environmental Controls: Handle in accordance with good industrial hygiene and safety practices. Do not discharge into drains, surface water, or soil
Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, characteristic
pH: Not applicable (insoluble in water)
Melting Point: ca. -20°C
Boiling Point: ca. 230-235°C
Flash Point: >150°C (closed cup)
Evaporation Rate: Not determined
Flammability: Not considered highly flammable
Vapor Pressure: < 0.01 hPa (20°C)
Vapor Density: Not determined
Density: ca. 1.05 g/cm³ (20°C)
Solubility in Water: Slightly soluble (ca. 0.2 g/l)
Partition Coefficient (n-octanol/water): log Pow ~4.18
Viscosity: 28 mPa.s at 25°C
Auto-Ignition Temperature: ca. 400°C
Chemical Stability: Stable under recommended storage conditions
Reactivity: No dangerous reactions expected during normal handling
Conditions to Avoid: High temperatures, open flames, strong oxidizers
Materials to Avoid: Strong acids, strong oxidizing agents
Hazardous Decomposition Products: Carbon oxides, possible traces of organic compounds
Acute Toxicity: Oral LD50 (rat): >5000 mg/kg
Skin Corrosion/Irritation: Not classified as skin irritant
Serious Eye Damage/Irritation: Not classified as eye irritant
Respiratory or Skin Sensitisation: Not sensitizing
Carcinogenicity: Not listed as a carcinogen
Reproductive Toxicity: No evidence of reproductive toxicity
Target Organ Effects: Not specifically identified
Ecotoxicity: Not considered harmful to aquatic life at normal concentrations
Biodegradability: Readily biodegradable under aerobic and anaerobic conditions
Bioaccumulation Potential: Low, based on measured log Pow
Mobility in Soil: Limited mobility, small water solubility
PBT/vPvB Assessment: Not classified as persistent, bioaccumulative, or toxic
Disposal of Product: Dispose of in accordance with local, regional, and national regulations. Do not pour into drains or waterways
Disposal of Packaging: Rinse empty containers and recycle or dispose of as hazardous waste according to regulations
Incineration: Incinerate at a licensed facility if permitted
Special Precautions: Avoid release to environment, do not dispose of together with household waste
UN Number: Not regulated
Transport Hazard Class: Not classified as hazardous for transport
Packing Group: Not assigned
Proper Shipping Name: Not regulated material
Environmental Hazards: Not a marine pollutant
Additional Transport Information: Standard chemical transport guidelines apply
Regulatory Status: Not classified as hazardous under EU CLP/GHS, US OSHA, or Canada WHMIS
REACH Registration: Yes, as required under EC 1907/2006
Inventory Listings: Listed in EINECS, TSCA, DSL, AICS, ENCS, and other national registries
International Regulations: Subject to usual workplace safety and chemical handling standards. No specific restrictions assigned
Other Information: Safety data complies with current legislative requirements, always update to latest guidance for workplace