Product Name: CITROFOL BII
Chemical Name: Tributyl O-acetylcitrate
Synonyms: Acetyl Tributyl Citrate, ATBC
Product Use: Plasticizer, used in food packaging, medical devices, children’s toys
Supplier: Jungbunzlauer
Emergency Contact: CHEMTREC, +1-800-424-9300
CAS Number: 77-90-7
EC Number: 201-067-0
REACH Registration Number: 01-2119457269-30
Hazard Classification: Not classified as hazardous under GHS
GHS Pictograms: None
Signal Word: None
Hazard Statements: Product can irritate eyes or skin on intense or repeated contact
Precautionary Statements: Avoid eye and prolonged skin contact, avoid inhalation of mist
Routes of Exposure: Eyes, skin, inhalation, ingestion
Chronic Hazards: Low, but repeated exposure might cause mild irritation
Chemical Name: Tributyl O-acetylcitrate
Concentration (%): ≥99%
CAS Number: 77-90-7
Impurities: Minimal; trace amounts of related esters
Other Ingredients: None significant for classification
Inhalation: Remove person to fresh air; seek medical advice if symptoms appear
Skin Contact: Wash thoroughly with soap and water; remove contaminated clothing
Eye Contact: Flush eyes with water for 10-15 minutes; seek medical attention if irritation persists
Ingestion: Rinse mouth; do not induce vomiting; consult medical personnel
Most Important Symptoms: Mild irritation of affected area
Medical Attention: Recommended if symptoms persist or significant exposure suspected
Suitable Extinguishing Media: Dry chemical, CO2, water spray, foam
Unsuitable Extinguishing Media: Direct water jet may spread the fire
Hazards: Combustion releases carbon oxides and smoke
Protective Equipment: Use self-contained breathing apparatus, full protective clothing
Specific Methods: Cool containers with water; prevent runoff from entering drains or waterways
Personal Precautions: Use protective gloves, safety goggles, protective clothing
Environmental Precautions: Prevent entry into sewers or waterways
Spill Clean-Up Methods: Absorb with inert material (sand, earth); collect for disposal in sealed containers
Decontamination: Clean spill site with water and detergent
Waste Disposal: Dispose via licensed waste contractors as per local regulations
Precautions for Handling: Avoid skin and eye contact; use only with adequate ventilation
Avoid: Prolonged or repeated contact with unprotected skin
Safe Storage Conditions: Store tightly closed in cool, dry, well-ventilated area
Incompatible Materials: Strong oxidizers, acids
Storage Stability: Store in original packaging, away from sunlight and heat sources
Workplace Exposure Limits: No occupational exposure limits established
Engineering Controls: Adequate general or local exhaust ventilation
Personal Protection: Chemical-resistant gloves, safety goggles, lab coat or apron
Respiratory Protection: Not required under normal use; use if aerosol likely
Hygiene Practices: Wash hands after handling; do not eat, drink, or smoke in work area
Appearance: Clear, oily liquid
Color: Colorless to pale yellow
Odor: Slight ester-like, faint
pH: Not applicable (non-aqueous)
Melting Point: -80°C
Boiling Point: 327°C
Flash Point: 195°C (closed cup)
Relative Density: 1.05 g/cm3 (20°C)
Solubility: Insoluble in water; soluble in organic solvents
Viscosity: 24-28 mPa·s (20°C)
Vapor Pressure: 0.02 Pa (20°C)
Chemical Stability: Stable under normal storage and handling conditions
Reactivity: Low under recommended conditions
Hazardous Reactions: None anticipated
Conditions to Avoid: Heat, open flames, strong oxidizing agents
Hazardous Decomposition Products: May produce carbon oxides (CO2, CO) under fire conditions
Acute Toxicity: Low; oral LD50 (rat) > 5,000 mg/kg
Inhalation Toxicity: Unlikely at room temperature due to low vapor pressure
Irritation: Mild eye and skin irritation possible
Sensitization: No evidence for sensitizing effects
Chronic Effects: No significant effects in animal studies
Carcinogenicity: Not listed by IARC, NTP, OSHA as carcinogenic
Mutagenicity: Negative in standard tests
Reproductive Toxicity: No adverse effects observed in reproductive studies
Ecotoxicity: Low aquatic toxicity; short-term tests on aquatic organisms show no acute effects
Persistence and Degradability: Readily biodegradable under aerobic conditions
Bioaccumulative Potential: Low; rapid biodegradation limits accumulation
Mobility in Soil: Limited, binds to soil particles
Other Effects: No known significant environmental effects in typical use scenarios
Waste Treatment Methods: Incineration or disposal at a licensed chemical waste facility
Contaminated Packaging: Rinse thoroughly before disposal or recycling
Local Regulations: Conform to local, state, and federal waste disposal requirements
Other Recommendations: Do not discharge into drains, surface waters, or soil
UN Number: Not regulated
Transport Hazard Classes: Not classified as hazardous for transportation
Packing Group: Not applicable
Marine Pollutant: No
Special Precautions: Transport in original packaging, keep upright and secure
Labeling Requirements: Not required based on current regulations
TSCA Inventory: Listed
REACH Status: Registered
OSHA Hazard Communication: Non-hazardous chemical under OSHA standards
Other Regulations: Compliant with FDA and EU regulations for food contact materials
Restrictions: No specific restrictions in place for intended uses
