Product Name: Lithium Citrate
Chemical Formula: C6H5Li3O7
CAS Number: 919-16-4
Recommended Use: Laboratory chemical, pharmaceutical manufacturing, specialty chemicals
Manufacturer/Supplier: Refer to container label
Emergency Contact Number: Refer to regional poison control centers or supplier
GHS Classification: Acute toxicity (oral, category 4), Skin and eye irritation
Signal Word: Warning
Hazard Statements: Harmful if swallowed; Causes skin and serious eye irritation
Pictograms: Exclamation mark
Routes of Exposure: Ingestion, inhalation, skin contact, eye contact
Potential Health Effects: Drowsiness, tremors, gastrointestinal distress, irritation to eyes and skin
Target Organs: Central nervous system, kidneys
Chemical Name: Lithium Citrate
Chemical Formula: C6H5Li3O7
CAS Number: 919-16-4
Concentration: Pure substance, 100%
Impurities: May contain trace hydration or contamination from manufacturing
Inhalation: Move person to fresh air, keep comfortable for breathing, seek medical attention if symptoms persist
Ingestion: Rinse mouth thoroughly, do not induce vomiting, seek medical assistance immediately
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, seek medical advice if irritation remains
Eye Contact: Rinse cautiously with plenty of water for at least 15 minutes, remove contact lenses if present, seek medical help
Acute and Delayed Symptoms: Nausea, vomiting, slurred speech, tremors, dizziness, skin redness, eye watering
Suitable Extinguishing Media: Water spray, dry chemical, carbon dioxide, foam
Unsuitable Extinguishing Media: None known for this material
Specific Hazards: Product may emit toxic fumes such as lithium oxide and carbon oxides under fire
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Explosion Data: No known explosion hazard; dust can form ignitable mixtures in air
Advice for Firefighters: Cool exposed containers with water if safe, avoid inhaling fumes
Personal Precautions: Do not touch or walk through spilled material without proper PPE; ventilate area
Protective Equipment: Chemical resistant gloves, safety goggles, dust mask or respirator
Environmental Precautions: Prevent entry into drains, waterways, and soil
Cleanup Methods: Sweep up using tools that avoid dust creation, collect in sealable container for disposal, flush area with water after cleanup
Additional Measures: Wash affected area, monitor for ongoing symptoms, dispose of waste according to local regulations
Safe Handling: Avoid contact with eyes, skin, clothing; prevent inhalation of powder or dust; use in a well-ventilated space
Storage Conditions: Store in tightly sealed container in a cool, dry, well-ventilated space
Incompatible Materials: Strong acids, strong oxidizers, moisture
Hygiene Measures: Wash hands thoroughly after handling, do not eat, drink, or smoke in handling area
Container Recommendations: Store away from incompatible substances; use non-reactive packaging materials
Occupational Exposure Limits: No established OSHA or ACGIH exposure limits for Lithium Citrate
Engineering Controls: Use local exhaust ventilation, process enclosures, or other engineering controls to limit exposure
Personal Protective Equipment:
Appearance: White, crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH: Approximately 8.0 (1% solution in water)
Melting Point: Decomposes before melting
Boiling Point: Not applicable
Flash Point: Not flammable
Evaporation Rate: Not applicable
Flammability: Non-flammable
Upper/Lower Flammability Limits: Not applicable
Vapor Pressure: Negligible
Vapor Density: Not applicable
Solubility: Soluble in water
Partition Coefficient (n-octanol/water): Not determined
Auto-ignition Temperature: Not self-igniting
Decomposition Temperature: No reliable data
Viscosity: Not applicable
Molecular Weight: 209.92 g/mol
Chemical Stability: Stable under normal conditions
Reactivity: Reacts with strong acids and oxidizing agents
Hazardous Reactions: Strong acid can produce heat and gas; reacts with moisture
Conditions to Avoid: Heat, sparks, open flame, moisture, strong oxidizing environments
Hazardous Decomposition Products: Lithium oxides, carbon monoxide, carbon dioxide
Polymerization: Does not occur
Acute Toxicity: Harmful if swallowed; symptoms can include nausea, vomiting, abdominal pain
Skin Corrosion/Irritation: Causes irritation, especially with repeated exposure
Serious Eye Damage/Irritation: Severe irritation, possible corneal injury
Respiratory Sensitization: May cause irritation to mucous membranes and upper respiratory tract
Specific Target Organ Toxicity: Nervous system and kidneys may be affected by high exposures
Chronic Effects: Long-term exposure can cause tremors and neurological symptoms
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
Reproductive Toxicity: Chronic lithium exposure associated with birth defects if used during pregnancy
Additional Information: Prolonged or repeated contact should be avoided to reduce risk of accumulation
Ecotoxicity: Low level of toxicity to aquatic organisms at typical release levels
Persistence and Degradability: Inorganic compound, not expected to degrade in the environment
Bioaccumulative Potential: Lithium ions do not bioaccumulate significantly in organisms
Mobility in Soil: High water solubility suggests mobility
Other Adverse Effects: Large releases may alter local ecosystem ionic balance, affecting sensitive species
Product Disposal: Dispose of as hazardous chemical waste following local regulations; do not pour down drains
Container Disposal: Thoroughly clean before recycling or disposal; follow regional protocols
Waste Treatment Methods: Incinerate or bury in permitted landfill after neutralization
Environmental Precautions: Prevent entry to water bodies, soil, sewers, and drains; consult waste disposal authority
UN Number: Not regulated for transport
Proper Shipping Name: Lithium citrate (not designated as hazardous in most jurisdictions)
Transport Hazard Class: Not classified
Packing Group: Not applicable
Marine Pollutant: No
Special Precautions for Transport: Keep container sealed and dry in transit, secure load to prevent tipping
U.S. Regulations: Not listed on SARA Title III, CERCLA, TSCA for hazard, but handle in accordance with OSHA safety standards
EU Regulations: Meets the criteria under REACH for chemical safety assessment, but not considered a candidate substance of very high concern
Canada: Not listed as hazardous under WHMIS
Other Regulations: Subject to local, state, and federal environmental and safety regulations
Label Elements: GHS-compliant labeling: hazard statement, precautionary statement, pictogram, signal word, and supplier identification required
