Material Safety Data Sheet: Potassium Dihydrogen Citrate

Identification

Product Name: Potassium Dihydrogen Citrate
Synonyms: Monopotassium citrate, Potassium acid citrate
Chemical Formula: C6H5K3O7·H2O
Molecular Weight: 230.22 g/mol
CAS Number: 866-84-2
Recommended Use: Laboratory reagent, food additive, pharmaceutical excipient
Supplier Name: [Supplier information]
Contact Details: [Supplier address, phone, emergency contact]

Hazard Identification

GHS Classification: Not classified as hazardous under GHS standards
Potential Health Effects: Mild skin or eye irritation might occur after contact; inhalation of dust may cause slight respiratory irritation; ingestion in large quantities could upset stomach
Label Elements: No pictograms or signal word required
Hazard Statements: May cause minor irritation to skin, eyes, and respiratory system
Precautionary Statements: Avoid breathing dust, wash hands after handling, use personal protective equipment to avoid contact

Composition / Information on Ingredients

Chemical Name: Potassium dihydrogen citrate
CAS Number: 866-84-2
Concentration: 99–100%

First Aid Measures

Inhalation: Get individual to fresh air, comfort breathing, seek medical attention if symptoms worsen
Skin Contact: Remove contaminated clothing, rinse area with soap and water, get medical help if irritation continues
Eye Contact: Rinse gently with water for several minutes, remove contact lenses, keep rinsing, consult a healthcare provider if irritation persists
Ingestion: Rinse mouth with water, drink water to dilute, avoid inducing vomiting, call a medical professional for advice if discomfort remains

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, foam, dry chemical, or carbon dioxide
Unsuitable Media: None known
Hazardous Combustion Products: May emit potassium oxides and carbon oxides in fire
Special Protective Equipment for Firefighters: Firefighters wear self-contained breathing apparatus, protective clothing
Special Hazards: Product itself not flammable but decomposition at high temperatures may release irritating fumes

Accidental Release Measures

Personal Precautions: Use protective gloves, avoid dust, ventilate area
Environmental Precautions: Prevent material from entering drains and waterways
Methods for Clean-Up: Collect spillage with shovel or vacuum, transfer to labeled container for disposal, wash area with water to remove residue

Handling and Storage

Handling: Avoid inhaling dust and contact with eyes and skin, wear appropriate personal protective gear, wash hands thoroughly after handling
Storage: Store in dry, well-ventilated location, keep in tightly closed containers, protect from moisture and incompatible substances such as acids and strong oxidizers, keep away from food and drink sources

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limits from OSHA, ACGIH, or other agencies
Engineering Controls: Use local exhaust ventilation where dust is produced
Personal Protection: Wear safety goggles, chemical resistant gloves, lab coat, respiratory protection if dust concentration increases
Hygiene Measures: Keep work area clean, wash hands before eating or drinking, avoid contact with unnecessary personnel

Physical and Chemical Properties

Appearance: White crystalline powder
Odor: Odorless
Odor Threshold: Not applicable
pH (solution): 4.0–5.0 (5% solution at 25°C)
Melting Point: 180–185°C (decomposition)
Boiling Point: Not applicable
Flash Point: Not combustible
Solubility: Soluble in water
Partition Coefficient: Not determined
Vapor Pressure: Not applicable
Density: Approximately 2.0 g/cm³
Viscosity: Not applicable
Evaporation Rate: Not relevant

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling conditions
Reactivity: Not reactive in dry, ambient conditions
Possibility of Hazardous Reactions: Hazardous polymerization does not occur
Conditions to Avoid: Excessive heat, moisture, exposure to acids or oxidizing agents
Incompatible Materials: Strong acids, strong oxidizers
Hazardous Decomposition Products: Potassium oxides, carbon oxides produced in extreme heat or fire

Toxicological Information

Acute Toxicity: Low toxicity; oral LD50 (rat) estimated to be greater than 2,000 mg/kg
Skin Contact: May cause mild irritation
Eye Contact: May irritate eyes
Ingestion: Large doses could cause gastrointestinal discomfort
Inhalation: Dust may irritate respiratory tract
Chronic Effects: No known significant effects or hazards
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
Mutagenicity: No data available
Reproductive Toxicity: No data available

Ecological Information

Ecotoxicity: Product considered to have low toxicity for aquatic organisms
Persistence and Degradability: Readily biodegradable in the environment
Bioaccumulative Potential: Not expected to accumulate in organisms
Mobility in Soil: High mobility due to water solubility
Other Adverse Effects: Large spills can impact pH of water bodies and may threaten aquatic life indirectly

Disposal Considerations

Waste Treatment Methods: Dispose of material in compliance with local, regional, and national regulations
Product Disposal: Reuse or recycle if possible, otherwise send to approved landfill or incinerator
Packaging Disposal: Rinse empty containers, recycle or dispose as inert waste according to regulations

Transport Information

UN Number: Not regulated
UN Proper Shipping Name: Not classified as hazardous for transport
Transport Hazard Class: None
Packing Group: None
Environmental Hazards: Not classified as marine pollutant
Special Precautions: Avoid generating dust in transit, keep containers upright and sealed

Regulatory Information

Safety, Health and Environmental Regulations: Not subject to major chemical regulatory listing (TSCA, EINECS, DSL)
SARA Title III: Not listed as a Hazardous Chemical
California Proposition 65: Product not listed
WHMIS Classification (Canada): Not classified as controlled
Other Regulations: Review local and national guidelines for workplace safety and workplace chemical use; ensure compliance with environmental discharge limits