Product Name: Vanadium Citrate
Chemical Formula: C12H14O12V4
Synonyms: Trivanadium Citrate, Vanadium(III) Citrate
CAS Number: 32081-67-1
Manufacturer: Supplier information available upon request
Recommended Uses: Catalysts, chemical research, nutritional supplements (only with strict professional guidance)
Restrictions: Not intended for drug, food, or home use
Emergency Contact: Refer to local regulations and supplier instructions
Hazard Class: Acute Toxicity (oral, inhalation), Eye and Skin Irritation
GHS Label Elements: Warning symbol: exclamation mark
Hazard Statements: Causes moderate skin irritation, serious eye irritation, harmful by inhalation or ingestion
Precautionary Statements: Do not breathe dust, wash thoroughly after handling, use only outdoors or in a well-ventilated area, wear protective gear
Acute Effects: Shortness of breath, coughing, redness or pain at contact sites
Chronic Effects: Extended exposure can lead to kidney issues, respiratory difficulties, and nervous system impacts
NFPA Rating: Health 2, Flammability 0, Reactivity 0, Special none
Main Component: Vanadium Citrate
Chemical Identity: Vanadium3+ complexed with citric acid
Concentration: 98–100%
Impurities: Trace metal ions, possible residual solvents
Additives: None present
Other Data: Does not include stabilizers or colorants
Inhalation: Move to fresh air, keep at rest, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, rinse skin immediately with water and mild soap for at least 15 minutes
Eye Contact: Rinse cautiously with clean water for several minutes, remove contact lenses if present, continue rinsing, seek medical help
Ingestion: Rinse mouth with water, never induce vomiting, get medical advice right away
Advice for Doctors: Treat symptomatically, monitor renal and respiratory function, provide supportive care as necessary
Flammability: Not flammable
Suitable Extinguishing Media: Use dry chemical powder, carbon dioxide, water fog, or foam
Hazardous Combustion Products: May release vanadium oxides, carbon oxides, irritating fumes
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Special Hazards: Runoff from fire control can contaminate water sources
Fire-Fighting Procedures: Move containers from fire area if possible without risk, cool exposed containers with water spray
Personal Precautions: Evacuate unnecessary personnel, use personal protective equipment, avoid dust generation, ensure adequate ventilation
Environmental Precautions: Prevent further leakage or spillage if safe, avoid release to drains or surface waters
Methods for Containment: Collect spill using a dustless method or vacuum with HEPA filter
Cleanup Methods: Clean area with damp cloth, dispose contaminated materials in accordance with regulations
Decontamination: Wash affected area with mild detergent and water after cleanup is complete
Safe Handling: Avoid contact with skin, eyes, and clothing; handle in exhaust-ventilated areas; keep containers sealed when not in use
Incompatible Materials: Strong acids, strong oxidizers, alkali metals
Storage Requirements: Store in cool, dry, and well-ventilated location; avoid humidity and exposure to direct light; use tightly closed, labeled containers
Shelf Life: Stable under recommended storage conditions for several years
Hygiene Practices: Wash hands thoroughly after handling, do not eat, drink, or smoke in storage or work areas
Control Parameters: Workplace exposure limits not established for vanadium citrate specifically; keep airborne concentrations as low as possible
Engineering Controls: Use with local exhaust ventilation, safety showers, eyewash stations
Personal Protection — Respiratory: Use NIOSH-approved particulate respirators in dusty conditions
Personal Protection — Skin: Wear protective gloves (nitrile or neoprene preferred), lab coat or other impervious clothing
Personal Protection — Eyes: Safety goggles or glasses with side-shields required
Personal Protection — Other: Remove contaminated clothing and wash before reuse; avoid bringing material home on work clothing
Appearance: Dark green to blue crystalline powder
Odor: Odorless
pH (1% solution): 4.0 - 6.0
Melting Point: Begins to decompose over 180°C
Boiling Point: Not applicable (decomposes)
Solubility: Soluble in water, insoluble in most organic solvents
Vapor Pressure: Negligible at room temperature
Density: 1.8–2.0 g/cm³
Particle Size: Fine powder, may create dust if handled improperly
Chemical Stability: Stable under recommended handling and storage conditions
Conditions to Avoid: High humidity, elevated temperatures, incompatible materials
Incompatible Materials: Strong acids (liberates toxic gases), strong bases, strong oxidizers
Hazardous Decomposition Products: Vanadium oxides, carbon oxides
Polymerization: Does not polymerize under normal conditions
Routes of Exposure: Inhalation, skin/eye contact, ingestion
Acute Toxicity (Animal Data): LD50 (oral, rat): estimated 300–450 mg/kg; LD50 (dermal, rabbit): not established
Possible Symptoms: Respiratory irritation, headache, nausea, stomach pain, vomiting, skin redness, eye damage
Chronic Effects: Repeated or prolonged exposure can harm respiratory tract, kidneys, possibly nervous system
Carcinogenicity: No IARC or NTP classification for this compound
Sensitization: Not expected, but repeated contact can cause dermatitis
Other Info: Pre-existing kidney, lung, or nervous system disorders may worsen with exposure
Aquatic Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Inorganic compound, does not readily degrade
Bioaccumulative potential: Vanadium can accumulate in aquatic organisms and plants
Soil Mobility: Depending on pH, may bind to soil or migrate to groundwater
Other Environmental Hazards: Spilled material can disrupt ecosystems if not controlled promptly
Waste Treatment Methods: Dispose through licensed chemical waste facilities with proper treatment
Disposal Containers: Use sealed, labeled, and chemically resistant containers
Prohibited Methods: Do not pour down sinks, drains, surface water, or regular trash
RCRA Status: May meet the criteria for hazardous waste depending on use and local regulations
Recommendations: Follow local, regional, and national waste regulations
UN Number: Not assigned for vanadium citrate
Transport Hazard Class: Not classified as dangerous goods for transport under ADR, IMDG, IATA as of current regulations
Packing Group: Not applicable
Transport Labels: Not required; still recommend “Hazardous Chemical” identification
Special Precautions: Prevent release during transport, use sealed packaging, keep away from food and feedstuffs, inform carriers about chemical hazards
GHS Classification: Regulated for acute toxicity and skin/eye irritation
OSHA: Not specifically listed, but should be handled as hazardous under OSHA Hazard Communication Standard
TSCA Status: Listed
EINECS/ELINCS: May be registered under European regulations
California Proposition 65: Not listed as of last update
Other Regulations: Follow relevant regional and national chemical safety legislation, workplace exposure standards, and reporting requirements for chemical spills
